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51.
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In this paper, the proposed is a quasi-flow constitutive model with strain-rate sensitivity for elastic plastic large deformation.
The model is based on the Quasi-flow Corner theory, and is suitable for the sheet metal forming process simulation with a
variable punch machine velocity. Uniaxial tensile tests and deep-drawing tests of a circular blank with square punch are carried
out and numerically simulated. The consistency between the experimental and the numerically simulated results shows the validity
of the present new constitutive model.
The project supported by the Scientific Foundation of National Outstanding Youth of China (10125208), the National Natural
Science Foundation of China (19832020), and the National Education Committee of China 相似文献
53.
Camilla Abbehausen Juliana F. CastroMarcelle B.M. Spera Tassiele A. HeinrichClaudio M. Costa-Neto Wilton R. LustriAndré L.B. Formiga Pedro P. Corbi 《Polyhedron》2011,30(13):2354-2359
A new gold(I) complex with 2-mercaptothiazoline (MTZ) with the coordination formula [AuCN(C3H5NS2)] was synthesized and characterized by chemical and spectroscopic measurements, DFT studies and biological assays. Infrared (IR) and 1H, 13C and 15N nuclear magnetic resonance (NMR) spectroscopic measurements indicate coordination of the ligand to gold(I) through the nitrogen atom. Studies based on DFT confirmed nitrogen coordination to gold(I) as a minimum of the potential energy surface with calculations of the hessians showing no imaginary frequencies. Thermal decomposition starts at temperatures near 160 °C, leading to the formation of Au0 as the final residue at 1000 °C. The gold(I) complex with 2-mercaptothiazoline (Au-MTZ) is soluble in dimethyl sulfoxide (DMSO), and is insoluble in water, methanol, ethanol, acetonitrile and hexane. The antibacterial activities of the Au-MTZ complex were evaluated by an antibiogram assay using the disc diffusion method. The compound showed an effective antibacterial activity against Staphylococcus aureus (Gram-positive) and Escherichia coli and Pseudomonas aeruginosa (Gram-negative) bacterial cells. Biological analysis for evaluation of the cytotoxic effect of the Au-MTZ complex was performed using HeLa cells derived from human cervical adenocarcinoma. The complex presented a potent cytotoxic activity, inducing 85% of cell death at a concentration of 2.0 μmol L−1. 相似文献
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55.
Rahul K. Verma Toshihiko Kuwabara Kwansoo ChungA. Haldar 《International Journal of Plasticity》2011,27(1):82-101
Recently non-proportional deformation has received increased attention from researchers working in the area of experimental and computational modeling of metal deformation. However, most of them are numerical in nature with limited experimental data available, making it further difficult to model non-proportional deformation. In the present work, two-stage uniaxial tests, along with uniaxial cyclic and biaxial tests for different stress ratios, have been performed to evaluate deformation behavior of ultra-low carbon high strength automotive steel. Behaviors like cross-effect and hardening stagnation, which are attributed to the evolution of complex dislocation structures, were observed in this steel. It was also noticed that this steel exhibits tension-compression asymmetry. As for constitutive modeling, a modified asymmetric yield function is proposed to be used with a combined isotropic-kinematic hardening model. Also methods to account for the hardening stagnation during reverse loading and the cross-effect during two-stage deformation are proposed. The resulting constitutive model showed reasonably good agreement with experimental results. 相似文献
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Gold nanoparticle arrays are fabricated for surface-enhanced Raman scattering (SERS) and the effect of the annealing temperature, the thickness of nanoparticle array and the exciting power on the SERS signals are investigated. The particle distribution and particle size are dense and uniform on the glass substrate when the 10 nm gold film was annealed at 250 °C and strong SERS signals for Rhodamine 6G were achieved via a 532 nm excitation with a 10 mW power. The SERS signal at 1650 cm−1 is enhanced more than 10 times as compared to that of the gold film without annealing. The strong SERS behavior of gold nanoparticle arrays may broaden the SERS applications in biomedical and analytical chemistry. 相似文献
59.
An excellent hole-transport material,1,3-diphenyl-5-(9-phenanthryl)-2-pyrazoline(DPPhP)for OLEDs was studied.This compound not only offers hlgh glass transition temperature(Tg=96℃),good film forming ability,and high HOMO energy level,but also displays excellent hole-transport property.The electrlumlnescent device with a simple structure of ITO/DPPhP(60nm)/AIQ(60mm)/LiF(0.8nm)/Al shows an external quantom efficiency as high as 1.6? 相似文献
60.
在综述掺氟高温超导体的主要类型与性质的基础上,分析了其中存在的无机结构及固态合成的化学动力学问题,探讨制备新型掺氟及全氟化物的高温超导体的可能性。 相似文献